I le kemisi, aemaise lava i le kemisi faʻaletino, o se vaega galue o se vaega faʻapitoa o atoms i totonu o se mole e nafa ma le faʻaogaina o vailaʻau faʻapitoa. Mafaufau i ai o le "vaega galue" poʻo le "vaega faʻamalamalamaga" o se mole mole. E tusa lava po o le a le tele poʻo le foliga o le vaega o totoe o le mole, o le vaega galue e amio i se auala faʻamaonia i gaioiga faʻamaʻi.
Aisea e Taua ai Vaega Fa'atino?
O vaega fa'atino e fa'atatau i mea totino ma fa'agaioiga o mea fa'aola. E fa'aogaina e le kemisi e fa'avasega ai molela'au fa'aola ma va'ai pe fa'apefea ona latou tali mai. Mo se fa'ata'ita'iga, 'ava malosi, acids, esters, ma ketones o lo'o iai uma vaega fa'atino eseese, ma e ese'ese le tali atu i gaioiga fa'a-kemikolo.
I le faailoaina o vaega galue i totonu o se mole, e mafai ona e:
● Va'ai po'o le a le mea o le a fa'aalia i gaioiga fa'ama'i.
● Malamalama i lona solubility (pe solo i le vai pe leai).
● Suʻesuʻe pe o le acidic po o le faavae.
● Va'ai le mea e pupuna ai pe liusuavai ai.
Fa'ata'ita'iga o Vaega Fa'atino masani
Se'i o tatou va'ava'ai i nisi o vaega fa'atino masani ile kemisi fa'aola:
1. Vaega Hydroxyl (-OH)
● E maua i le ava malosi.
● Faia molelaʻau polar ma mafai ona fausia fusi hydrogen.
● Faataitaiga: Ethanol (CH₃CH₂OH)
2. Vaega Carbonyl (C=O)
● E maua i ketones ma aldehydes.
● O se kaponi e fusia lua i se atoma okesene.
● Faataitaiga:
Ketone: Acetone (CH₃COCH₃)
Aldehyde: Formaldehyde (HCHO)
3. Carboxyl Group (-COOH)
● E maua i le carboxylic acids.
● Fai le mole mole oona.
● Faʻataʻitaʻiga: Acetic acid (CH₃COOH), o le suka autu i le vineka.
4. Vaega Amino (-NH₂)
● E maua i amine ma amino acids.
● E mafai ona galue o se faavae ma talia protons.
● Faataitaiga: Glycine, o se amino acid.
5. Ester Group (-COO-)
● E maua i esters.
● E masani ona avatu i fualaʻau manogi manogi.
● Fausia mai le acid ma le ava malosi.
● Fa'aa'oa'oga: Ethyl acetate (fa'aoga i le fa'a'a'e fao).
6. Eteru Vaega (ROR)
● Atom o le okesene e fesootaʻi atu i vaega kaponi se lua.
● taatele i solvents.
● Faaaʻoaʻoga: Diethyl ether.
7. Vaega Halide (CX)
● O fea X = o se halogen pei o F, Cl, Br, poʻo I.
● E maua i alkyl halides.
● Faʻaaogaina i pusaaisa ma faʻafefe mu.
8. Sulfhydryl Group (-SH)
● E maua i thiols.
● E tutusa ma le hydroxyl ae iai le sulfur.
● Taua i le fausaga o porotini (disulfide bonds).
Vaega Fa'atino ma Gaoioiga
O le iai o se vaega fa'atino fa'apitoa i totonu o se mole e tele lava ina fa'amoemoe pe fa'afefea ona tali atu lena mole. Faataitaiga:
● Alcohols (-OH) e mafai ona faʻamama e fai ai alkenes.
● Carboxylic acids (-COOH) e mafai ona gaoioi ma ava malosi e fai ai ester.
● Amines (-NH₂) e mafai ona avea ma faavae ma talia ion hydrogen.
O lenei amio fa'apitoa e matua'i aoga tele i kemisi fa'akomepiuta, fa'asologa o vaila'au, ma mea fa'asaienisi.
Vaega Fa'atino i Biological Molecules
O vaega galue o le ki foi lea i le olaga. I le biochemistry, o le fausaga ma le aoga o polotini, DNA, carbohydrates, ma gaʻo e faʻalagolago tele i vaega galue o loʻo i ai.
● O polotini e iai vaega amino (-NH₂) ma carboxyl (-COOH).
● O le carbohydrate e masani ona iai vaega hydroxyl (-OH) ma carbonyl (C=O).
● O le DNA ma le RNA e iai vaega o le phosphate (-PO₄) ma faavae e iai le nitrogen.
O nei vaega e faʻatagaina mole mole ola e fegalegaleai, fausia faʻamauga hydrogen, faʻafeiloaʻi le malosi, ma isi mea.
Fa'afefea ona Fa'aaoga e Chemists Vaega Fa'atino
E masani ona fa'aogaina e le au kemisi le fa'ailoga vaega fa'atino pe a tusia pe fa'aigoaina mole mole. I gaioiga fa'a-kemikolo, e mafai ona latou fa'asino i fa'agaioiga a le vaega o lo'o a'afia ai. Faataitaiga:
● O le “Alcohol oxidation” e faasino i gaioiga e aofia ai vaega -OH.
● O le “nucleophilic substitution” e masani ona aofia ai vaega o le halide.
Latou te fa'aogaina fo'i su'esu'ega vaega fa'atino e fa'ailoa ai mea e le o iloa e fa'aaoga ai metotia e pei o le infrared (IR) spectroscopy ma le nuclear magnetic resonance (NMR), talu ai o vaega ta'itasi e mitiia le malosi i se auala tulaga ese.
Aotelega
O se vaega galue o se vaega patino o atoms i totonu o se mole e tuʻuina atu i le mole ona uiga patino ma le gaioiga. O i latou ia o le fa'avae o le kemisi fa'aletino, e maua ai se auala e fa'avasega ma va'ai ai le amio a molela'au lavelave. Mai 'ava malosi i le DNA lavelave, o vaega fa'atino e fesoasoani e fa'amalamalama le fausaga, galuega, ma le fa'agaoioiga o vaila'au fa'ama'i. O le malamalama ia i latou e taua i le aʻoaʻoina o kemisi, aemaise lava i vaega e pei o vailaʻau, biology, ma kemisi fale gaosi oloa.
Taimi meli: Iuni-20-2025

